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(1) As per Joseph C Reynolds et al., “Mitochondria are chief metabolic organelles with strong implications in cell aging that also coordinate broad physiological functions, in part, using peptides that are encoded within their independent genome.”(4) The peptide endogenous expression has also been posited to be boosted via physical activity, potentially enhancing cellular metabolism

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That matters because nicotinamide can participate in NAD+ salvage pathways, while SAM is used throughout the cell for methylation reactions